Silk
is a natural protein fiber, some forms of which can be woven into textiles. The best-known type of silk is obtained from cocoons made by the larvae of the mulberry silkworm Bombyx mori
reared in captivity (sericulture). The shimmering appearance of silk is due to the triangular prism-like structure of the silk fiber which allows silk cloth to refract incoming light at different angles thus producing different colors.
Silks are produced by several other insects, but only the silk of moth caterpillars has been used for textile manufacture. There has been some research into other silks, which differ at the molecular level. Silks are mainly produced by the larvae of insects that complete metamorphosis, but also by some adult insects such as webspinners. Silk production is especially common in the Hymenoptera (bees, wasps, and ants), and is sometimes used in nest construction. Other types of arthropod produce silk, most notably various arachnids such as spiders (see spider silk).
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Wild silk
A variety of
wild silks, produced by
caterpillars other than the mulberry silkworm have been known and used in
China,
South Asia, and
Europe since ancient times. However, the scale of production was always far smaller than that of cultivated silks. They differ from the domesticated varieties in color and texture, and cocoons gathered in the wild usually have been damaged by the emerging moth before the cocoons are gathered, so the silk thread that makes up the cocoon has been torn into shorter lengths. Commercially reared silkworm pupae are killed by dipping them in boiling water before the adult moths emerge, or by piercing them with a needle, allowing the whole cocoon to be unraveled as one continuous thread. This permits a much stronger cloth to be woven from the silk. Wild silks also tend to be more difficult to dye than silk from the cultivated silkworm.
History
China
Silk fabric was first developed in ancient
China, possibly as early as 6000 BC and definitely by 3000 BC. Legend gives credit for developing silk to a Chinese empress,
Lei Zu (Hsi-Ling-Shih, Lei-Tzu). Silks were originally reserved for the Kings of China for their own use and gifts to others, but spread gradually through
Chinese culture and trade both geographically and socially, and then to many regions of
Asia. Silk rapidly became a popular luxury fabric in the many areas accessible to Chinese merchants because of its texture and luster. Silk was in great demand, and became a staple of pre-
industrial international
trade. In July 2007, archeologists discovered intricately woven and dyed silk
textiles in a tomb in
Jiangxi province, are dated to the Eastern
Zhou Dynasty, roughly 2,500 years ago.
[1] Although historians have suspected a long history of a formative textile industry in ancient China, this find of silk textiles employing "complicated techniques" of weaving and dyeing provides direct and concrete evidence for silks dating before the
Mawangdui-discovery and other silks dating to the
Han Dynasty (202 BC-220 AD).
The first evidence of the silk trade is the finding of silk in the hair of an
Egyptian
mummy of the 21st dynasty, c.1070 BC . Ultimately the silk trade reached as far as the
Indian subcontinent, the
Middle East,
Europe, and
North Africa. This trade was so extensive that the major set of trade routes between Europe and Asia has become known as the
Silk Road.
The
Emperors of China strove to keep knowledge of
sericulture secret to maintain the Chinese
monopoly. Nonetheless sericulture reached
Korea around 200 BC, about the first half of the 1st century AD had reached ancient
Khotan [2], and by AD 300 the practice had been established in India.
Thailand
Silk is produced, year round, in Thailand by two types of silkworms, the cultured Bombycidae and wild Saturniidae. Most production is after the rice harvest in the southern and northeast parts of the country. Women traditionally weave silk on hand looms, and pass the skill on to their daughters as weaving is considered to be a sign of maturity and eligibility for marriage. Thai silk textiles often use complicated patterns in various colors and styles. Most regions of Thailand have their own typical silks. A single thread filament is too thin to use on its own so women combine many threads to produce a thicker, usable fiber. They do this by hand-reeling the threads onto a wooden spindle to produce a uniform strand of raw silk. The process takes around 40 hours to produce a half kilogram of Thai silk.
thumb
Many local operations use a reeling machine for this task, but there are silk threads that are still hand-reeled. The difference is that hand-reeled threads produce three grades of silk: two fine grades that are ideal for lightweight fabrics and a thick grade for heavier material.
The silk fabric is soaked in hot water and bleached before dyeing in order to remove the natural yellow coloring of Thai silk yarn. To do this, skeins of silk thread are immersed in large tubs of hydrogen peroxide. Once washed and dried, the silk is then woven using a traditional hand operated loom.
[3]
India
Silk, known as
Pattu
in southern parts of
India and
Resham
in Hindi/Urdu (from Persian), has a long history in India. Recent archaeological discoveries in
Harappa and
Chanhu-daro suggest that
sericulture, employing
wild silk threads from native
silkworm species, existed in
South Asia during the time of the
Indus Valley Civilisation, roughly contemporaneous with the earliest known silk use in China.
[4] Silk is widely produced today. India is also the largest consumer of silk in the world. The tradition of wearing silk sarees in marriages by the brides is followed in southern parts of India. Silk is worn by people as a symbol of royalty while attending functions and during festivals. Historically silk was used by the upper classes, while cotton was used by the poorer classes. Today silk is mainly used in
Bhoodhan Pochampally (also known as
Silk City),
Kanchipuram, Dharmavaram, Mysore, etc. in South India and
Banaras in the North for manufacturing
garments and
sarees. "Murshidabad silk", famous from historical times, is mainly produced in Malda and Murshidabad district of West Bengal and woven with hand looms in Birbhum and Murshidabad district. Another place famous for production of silk is
Bhagalpur. The silk from Kanchi is particularly well-known for its classic designs and enduring quality. The silk is traditionally hand-woven and hand-dyed and usually also has silver threads woven into the cloth. Most of this silk is used to make saris. The saris usually are very expensive and vibrant in color. Garments made from silk form an integral part of Indian weddings and other celebrations. In the northeastern state of
Assam, three different types of silk are produced, collectively called
Assam silk: Muga, Eri and Pat silk. Muga, the golden silk, and Eri are produced by silkworms that are native only to Assam. The heritage of silk rearing and weaving is very old and continues today especially with the production of Muga and Pat
riha
and
mekhela chador
, the three-piece silk
saris woven with traditional motifs.
Mysore Silk Sarees
, which are known for their soft texture, last many years if carefully maintained.
Ancient Mediterranean
In the
Odyssey, 19.233, when Odysseus, while pretending to be someone else, is questioned by Penelope about her husband's clothing, he says that he wore a shirt "gleaming like the skin of a dried onion" (varies with translations, literal translation here)
[5] which could refer to the lustrous quality of silk fabric. The
Roman Empire knew of and traded in silk. During the reign of emperor
Tiberius,
sumptuary laws were passed that forbade men from wearing silk garments, but these proved ineffectual.
[6]
Despite the popularity of silk, the secret of silk-making only reached Europe around AD 550, via the
Byzantine Empire. Legend has it that monks working for the emperor
Justinian I smuggled silkworm eggs to
Constantinople in hollow canes from China. All top-quality looms and weavers were located inside the Palace complex in
Constantinople and the cloth produced was used in imperial robes or in diplomacy, as gifts to foreign dignitaries. The remainder was sold at very high prices.
Islamic world
In
Islamic teachings, Muslim men are forbidden to wear silk. Many religious jurists believe the reasoning behind the prohibition lies in avoiding clothing for men that can be considered feminine or extravagant.
[7] There are disputes regarding the amount of silk a fabric can consist of (i.e., whether a small decorative silk piece on a cotton caftan is permissible or not) for it to be lawful for men to wear but the dominant opinion of most Muslim scholars is that the wearing of silk for men is forbidden.
Despite injunctions against silk for men, silk has retained its popularity in the Islamic world because of its permissibility for women. The Muslim
Moors brought silk with them to Spain during their conquest of the Iberian Peninsula.
Medieval and modern Europe
Venetian merchants traded extensively in silk and encouraged silk growers to settle in
Italy. By the 13th century, Italian silk was a significant source of trade. Since that period, the silk worked in the
province of Como has been the most valuable silk in the world. The wealth of
Florence was largely built on textiles, both
wool and silk, and other cities like
Lucca also grew rich on the trade. Italian silk was so popular in Europe that
Francis I of France invited Italian silk makers to France to create a French silk industry, especially in
Lyon. Mass emigration (especially of
Huguenots) during periods of religious dispute had seriously damaged French industry and introduced these various textile industries, including silk, to other countries.
James I attempted to establish silk production in England, purchasing and planting 100,000 mulberry trees, some on land adjacent to
Hampton Court Palace, but they were of a species unsuited to the silk worms, and the attempt failed. British enterprise also established silk filature in
Cyprus in 1928. In England in the mid 20th Century, silk was produced at Lullingstone Castle in Kent. Silkworms were raised and reeled under the direction of Zoe Lady Hart Dyke. Production started elsewhere later. In
Italy, the
Stazione Bacologica Sperimentale was founded in
Padua in 1871 to research sericulture. In the late 19th century, China, Japan, and Italy were the major producers of silk. The most important cities for silk production in Italy were
Como and
Meldola [8] (
Forlì). In medieval times, it was common for silk to be used to make elaborate casings for bananas and other fruits.
Silk was expensive in Medieval Europe and used only by the rich. Italian merchants like
Giovanni Arnolfini became hugely wealthy trading it to the Courts of Northern Europe.
North America
James I of England introduced silk-growing to the American colonies around 1619, ostensibly to discourage
tobacco planting. The
Shakers in Kentucky adopted the practice as did a cottage industry in New England.
[9] In the 1800s a new attempt at a silk industry began with European-born workers in
Paterson, New Jersey, and the city became a US silk center, although Japanese imports were still more important.
World War II interrupted the silk trade from
Japan. Silk prices increased dramatically, and US industry began to look for substitutes, which led to the use of
synthetics such as
nylon. Synthetic silks have also been made from
lyocell, a type of
cellulose fiber, and are often difficult to distinguish from real silk (see
spider silk for more on synthetic silks).
Properties
thumb in
Changsha,
Hunan province,
China, from the
Western Han Dynasty, 2nd century BC
Physical properties
Silk fibers from the
Bombyx mori
silkworm have a triangular
cross section with rounded corners, 5-10 µm wide. The fibroin heavy chain is mostly composed of beta-sheets due to a 59-mer aminoacid repeat sequence GAGAGSGAAG[SGAGAG]
8Y with some variations.
[10] The flat surfaces of the fibrils reflect light at many different angles, giving silk a natural shine. The cross-section from other silkworms can vary in shape and diameter: crescent-like for
Anaphe
and elongated wedge for
tussah
. Silkworm fibers are naturally extruded from two silkworm glands as a pair of primary filaments (brin) which are stuck together, with sericin proteins acting like glue, to form a bave. Bave diameters for tussah silk can reach 65 µm. See cited reference for cross-sectional SEM photographs.
[11]
Silk has a smooth, soft texture that is not slippery, unlike many
synthetic fibers. Its
denier is 4.5 g/d when dry and 2.8-4.0 g/d when moist.
Silk is one of the strongest natural fibers but loses up to 20% of its strength when wet. It has a good moisture regain of 11%. Its elasticity is moderate to poor: if elongated even a small amount it remains stretched. It can be weakened if exposed to too much sunlight. It may also be attacked by insects, especially if left dirty.
Silk is a poor conductor of electricity and thus susceptible to static cling.
Unwashed silk chiffon may shrink up to 8% due to a relaxation of the fiber macrostructure. So silk should either be pre-washed prior to garment construction, or dry cleaned. Dry cleaning may still shrink the chiffon up to 4%. Occasionally, this shrinkage can be reversed by a gentle steaming with a press cloth. There is almost no gradual shrinkage or shrinkage due to molecular-level deformation.
Chemical properties
Silk is made up of the
amino acids
Gly-
Ser-Gly-
Ala and forms
Beta pleated sheets. Interchain H-bonds are formed while side chains are above and below the plane of the H-bond network.
The high proportion (50%) of glycine, which is small, allows tight packing and the fibers are strong and resistant to stretching. The tensile strength is due to the many interseeded hydrogen bonds. Since the protein forms a Beta sheet, when stretched the force is applied to these strong bonds and they do not break.
Silk is resistant to most mineral acids but will dissolve in sulfuric acid. It is yellowed by perspiration.
Uses
Image:Turkeye.Urgüp02.jpg|200px|thumb
|Silk filaments being unraveled from silk cocoons,
Cappadocia,
Turkey, 2007.
Silk's good
absorbency makes it comfortable to wear in warm weather and while active. Its low conductivity keeps warm air close to the skin during cold weather. It is often used for clothing such as
shirts,
blouses, formal
dresses, high fashion clothes,
negligees,
pyjamas,
robes,
skirtsuits, sun dresses and
kimonos.
Silk's elegant, soft luster and beautiful drape makes it perfect for many
furnishing applications. It is used for
upholstery, wall coverings, window treatments (if blended with another fiber),
rugs,
bedding and wall hangings.
While on the decline now, due to artificial fibers, silk has had many industrial and commercial uses;
parachutes, bicycle
tires,
comforter filling and
artillery gunpowder bags.
From the
blackpowder era, until roughly
World War I, early
bulletproof vests were made from silk.
A special manufacturing process which removes the outer irritant sericin coating of the silk makes it suitable as non-absorbable
surgical sutures. This process has also recently led to the introduction of specialist silk underclothing for children and adults with
eczema where it can significantly reduce
itch.
Silk cloth is also used as a material on which to write and paint.
Production
The cultivation of silk is called sericulture. Over 30 countries produce silk, the major ones are
China (54%) and
India (14%).
"In order to produce 1 kg of silk, 104 kg of mulberry leaves need to be eaten by 3000 silkworms. It takes about 5000 silkworms to make a pure silk kimono." [12]
Top Ten Cocoons (Reelable) Producers — 2005
|
Country
| Production (Int $1000)
| Footnote
| Production (1000 kg)
| Footnote
|
| 978,013
| C
| 290,003
| F
|
| 259,679
| C
| 77,000
| F
|
| 57,332
| C
| 17,000
| F
|
| 37,097
| C
| 11,000
| F
|
|
|
History of Iran
Empires of Persia · Kings of Persia
| BCE
|
Sialk civilization
| 7500–1000
| Jiroft civilization (Aratta)
| 4000–?
| Proto-Elamite civilization
| 3200–2800
| Elamite dynasties
| 2800–550
| Kassites
| 16th–12th cent.
| Kingdom of Mannai
| 10th–7th cent.
| Median Empire
| 728–550
| Achaemenid Empire
| 550–330
| Seleucid Empire
| 330–150
| Parthian Empire
| 248–CE 226
|
| CE
| Sassanid Empire
| 226–651
| Afrighid dynasty
| ?–995
| Patriarchal Caliphate
| 637–651
| Umayyad Caliphate
| 661–750
| Abbasid Caliphate
| 750–1258
| Tahirid dynasty
| 821–873
| Alavid dynasty
| 864–928
| Sajid dynasty
| 889/890–929
| Saffarid dynasty
| 861–1003
| Samanid dynasty
| 875–999
| Ziyarid dynasty
| 928–1043
| Buyid dynasty
| 934–1055
| Sallarid
| 942–979
| Ma'munids
| 995-1017
| Ghaznavid Empire
| 963–1187
| Ghori dynasty
| 1149–1212
| Seljukid Empire
| 1037–1194
| Khwarezmid dynasty
| 1077–1231
| Ilkhanate
| 1256–1353
| Muzaffarid dynasty
| 1314–1393
| Chupanid dyansty
| 1337–1357
| Jalayerid dynasty
| 1339–1432
| Timurid Empire
| 1370–1506
| Qara Qoyunlu Turcomans
| 1407–1468
| Aq Qoyunlu Turcomans
| 1378–1508
| Safavid dynasty
| 1501–1722*
| Hotaki dynasty
| 1722–1729
| Afsharid dynasty
| 1736–1750
| Zand dynasty
| 1750–1794
| Qajar dynasty
| 1781–1925
| Pahlavi dynasty
| 1925–1979
| Iranian Revolution
| 1979
| The Interim Government of Iran
| 1979–1980
| Islamic Republic of Iran
| since 1980
| * or 1736
| Timeline
|
[ edit]
|
20,235
| C
| 6,000
| F
|
| 16,862
| C
| 5,000
| F
|
| 10,117
| C
| 3,000
| F
|
| 5,059
| C
| 1,500
| F
|
| 3,372
| C
| 1,000
| F
|
| 2,023
| C
| 600
| F
|
No symbol = official figure,F = FAO estimate, * = Unofficial figure, C = Calculated figure;
Production in Int $1000 have been calculated based on 1999-2001 international prices
Source:
|
Cultivation
Silk moths lay eggs on specially prepared paper. The eggs hatch and the caterpillars (silkworms) are fed fresh mulberry leaves. After about 35 days and 4 moltings, the caterpillars are 10,000 times heavier than when hatched, and are ready to begin spinning a cocoon. A straw frame is placed over the tray of caterpillars, and each caterpillar begins spinning a cocoon by moving its head in a "figure 8" pattern. Two glands produce liquid silk and force it through openings in the head called spinnerets. Liquid silk is coated in sericin, a water-soluble protective gum, and solidifies on contact with the air. Within 2–3 days, the caterpillar spins about 1 mile of filament and is completely encased in a cocoon. The silk farmers then kill most caterpillars by heat, leaving some to
metamorphose into moths to breed the next generation of caterpillars.
Animal rights
As the process of harvesting the silk from the cocoon kills the larvae, sericulture has been criticized in the early 21st century by
animal rights activists, especially since
artificial silks are available.
[13]
Mahatma Gandhi was also critical of silk production based on the
Ahimsa philosophy "not to hurt any living thing." This led to Gandhi's promotion of cotton spinning machines, an example of which can be seen at the Gandhi Institute. He also promoted
Ahimsa silk
,
wild silk made from the cocoons of wild and semi-wild silk moths.
[14] Ahimsa silk is promoted in parts of Southern India for those who prefer not to wear silk produced by killing silkworms.
[15] [16] [17] [18]
See also
- History of silk
- Silk Road
- Silk waste
- Mommes, the traditional density unit for silk.
- Rayon
- Art silk
- Thai silk
- Spider silk (with a discussion of synthetic silk)
- Tenun Pahang Diraja, famous woven silk fabric of Pahang, Malaysia.
- Silk in the Indian subcontinent
- International Year of Natural Fibres 2009
Footnotes
References
- Chinese archaeologists make ground-breaking textile discovery in 2,500-year-old tomb
- Hill, John E. 2003. "Annotated Translation of the Chapter on the Western Regions according to the ''Hou Hanshu''." 2nd Draft Edition. Appendix A. [1]
- About Thai silk from World of Thai Silk (commercial)
- New evidence for early silk in the Indus civilisation
- Odyssey '''19''' 233-234:
t?? d? ??t??' ????sa pe?? ???? s??a??e?ta, ???? te ???µ???? ??p?? ??ta ?s?a?????· = "And I [= Odysseus
- Annals
- Silk: Why It Is Haram for Men
- The Silkworm Museum, Meldola
- Mansfield Historical Society
- "Handbook of Fiber Chemistry", Menachem Lewin, Editor, 3rd ed., 2006, CRC press, ISBN: 0824725654
- "Handbook of Fiber Chemistry", Menachem Lewin, Editor, 2nd ed.,1998, Marcel Dekker, pp. 438-441, ISBN: 0824794710
- Fritz and Cant (1986), p. 104.
- Down and Silk: Birds and Insects Exploited for Fabric
- "Mahatma Gandhi: 100 years", 1968, p. 349
- Silk Moths Fly Free Kusuma Rajaiah's Ahimsa project.
- Silk saree without killing a single silkworm Another article about Rajaiah and his methods.
- Peace Silk The main source for cruelty-free silk in the United States.
- Why 'Peace Silk' Doesn't Add Up Critical article pointing out that if pupae are allowed to live their descendants may dessicate or starve to death.